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POLYMER TECHNOLOGY​


POLYMER TECHNOLOGY SYLLABUS

(These syllabus may change from time to time. Please check with the relevant Public Service Commission websites for any changes in the syllabus)​
  • Raw materials, monomers, homopolymers, copolymers
  • Vinyl polymers, polymer chemistry, primary and secondary bonds
  • Properties affected by primary bonds; physical properties affected by secondary bonds
  • Free radical polymerization: reaction and termination rates using physical chemistry models; ionic, condensation and mixed mode polymerization
  • Physical structure of polymers: semi-crystalline, amorphous, and rubbery states. Chain branching, networking in polymers.
  • Iso-free volume theory: deformation of polymers - glassy and viscoelastic; molecular statistics of rubbery states
  • Tensile, shear, compression and impact properties
  • Effect of temperature and strain rates in polymers.
  • Rheology: relationship between molecular weight, temperature and shear rates.
  • Effect of additives.
  • Structure-property correlation in glassy, semicrystalline and oriented polymers
  • Polymer manufacturing and applications. Commodity and specialty plastics; Nanopolymers, conducting polymers. 

POLYMER TECHNOLOGY MCQs

​1. Which of the following is a trifunctional monomer?
 A:-Propylene
 B:-Butadiene
 C:-Glycerol
 D:-Glycol
 Correct Answer:- Option-C

2. Polymer molecular weight is equal to repeat unit molecular weight times n, where n is
 A:-Degree of polymerization
 B:-Functionality
 C:-Molecular weight distribution
 D:-Extent of polymerization
 Correct Answer:- Option-A

3. Below the glass transition temperature the free volume is
 A:-Maximum
 B:-Zero
 C:-One
 D:-Minimum
 Correct Answer:- Option-D

4. Which of the following is a first order process?
 A:-Solidification
 B:-Vapourization
 C:-Melting
 D:-All of these
 Correct Answer:- Option-D

5. Glass transition temperature of polyisoprene is
 A:-Below room temperature
 B:-Above room temperature
 C:-Zero
 D:-None of these
 Correct Answer:- Option-A

6. A SBR is an example of
 A:-Graft copolymer
 B:-Random copolymer
 C:-Block copolymer
 D:-Homopolymer
 Correct Answer:- Option-B

7. Hilderbrand is the unit of
 A:-Flory interaction parameter
 B:-Enthalpy
 C:-Solubility parameter
 D:-None of these
 Correct Answer:- Option-C

8. For a polymer prepared by free radical polymerization
 A:-Mw > Mn
 B:-Mw < Mn
 C:-Mz < Mn
 D:-Mn = Mw = Mz
 Correct Answer:- Option-A

9. Polydispersity index is said to be 1 when
 A:-Mw = Mn
 B:-Mw > Mz
 C:-Mz > Mz+1
 D:-None of these
 Correct Answer:- Option-A

10. Thermoplastic polyurethane is a
 A:-Thermoplastic
 B:-Elastomer
 C:-Thermoplastic elastomer
 D:-Thermoset
 Correct Answer:- Option-C

11. For EPDM the unsaturation is in the
 A:-Main chain
 B:-Branches
 C:-Pendent groups
 D:-All of these
 Correct Answer:- Option-C

12. The monomers of butyl rubber are
 A:-Butadiene and isoprene
 B:-Butadiene and 1-butene
 C:-Isoprene and 1-butene
 D:-None of these
 Correct Answer:- Option-D

13. The property that is lowered by increasing CN content of NBR is
 A:-Oil resistance
 B:-Low temperature flexibility
 C:-High temperature resistance
 D:-None of these
 Correct Answer:- Option-B

14. The EPM is not cured by
 A:-Sulphur
 B:-Peroxide
 C:-Radiation
 D:-Oxime
 Correct Answer:- Option-A

15. Fluorocarbons are known for
 A:-High temperature resistance
 B:-Ozone resistance
 C:-Oil resistance
 D:-All of these
 Correct Answer:- Option-D

16. Nylon 66 melts at (deg C)
 A:-219
 B:-249
 C:-269
 D:-289
 Correct Answer:- Option-C

17. In unsaturated polyester the monomer that is commonly used to give crosslinking sites is
 A:-Fumaric acid
 B:-Terephthalic acid
 C:-Itaconic acid
 D:-Maleic anhydride
 Correct Answer:- Option-D

18. Neoprene is commonly cured with
 A:-Sulphur
 B:-Metal oxide
 C:-Peroxide
 D:-Radiation
 Correct Answer:- Option-B

19. An example of amorphous polymer is
 A:-UPVC
 B:-PMMA
 C:-Polystyrene
 D:-All of these
 Correct Answer:- Option-D

20. For polymer containing OH group a major absorption peak is expected at (wave number)
 A:-3400
 B:-3000
 C:-2450
 D:-1700
 Correct Answer:- Option-A

21. Which of the following is commonly use to estimate crystallinity?
 A:-NMR
 B:-TGA
 C:-X ray
 D:-TMA
 Correct Answer:- Option-C

22. Tan delta is defined as
 A:-Loss modulus / storage modulus
 B:-Storage modulus / loss modulus
 C:-Logarithmic decay / phase angle
 D:-Phase angle / storage modulus
 Correct Answer:- Option-A

23. Resilience is inversely related to
 A:-Compression set
 B:-Heat build up
 C:-Tension set
 D:-All of these
 Correct Answer:- Option-B

24. Tear strength is optimum at
 A:-Optimum cure
 B:-Slight under cure
 C:-Slight over cure
 D:-None of these
 Correct Answer:- Option-B

25. A high value of tan delta indicates
 A:-good traction
 B:-good mileage
 C:-low heat build up
 D:-All of these
 Correct Answer:- Option-A
26. Which rubber gives high tear resistance?
 A:-PBD
 B:-SBR
 C:-IIR
 D:-NR
 Correct Answer:- Option-D

27. A DSC can measure
 A:-Heat capacity
 B:-Glass transition temperature
 C:-Melting point
 D:-All of these
 Correct Answer:- Option-D

28. A parison is used in
 A:-Blow moulding
 B:-Transfer moulding
 C:-Compression moulding
 D:-None of these
 Correct Answer:- Option-A

29. PET is not used in extrusion blow moulding because
 A:-High viscosity
 B:-High die swell
 C:-Low melt strength
 D:-Shark skin effect
 Correct Answer:- Option-C

30. Which of the following is amenable to reaction injection moulding?
 A:-PET
 B:-TPU
 C:-NYLON
 D:-PU
 Correct Answer:- Option-D

31. RRIM is used when
 A:-Good strength is needed
 B:-Fast reaction is needed
 C:-High volume output is needed
 D:-None of these
 Correct Answer:- Option-A

32. In a two roll mill the shear rate is adjusted by
 A:-reducing nip gap
 B:-increasing roll speed ratio
 C:-both of these
 D:-none of these
 Correct Answer:- Option-C

33. The effect of roll bending in calendaring operation is reduced by
 A:-Roll crossing
 B:-Roll crowning
 C:-Roll bending
 D:-All of these
 Correct Answer:- Option-D

34. The role of a plug in a plug-assisted thermoforming is to help
 A:-Maintain uniform thickness
 B:-Permit deep drawing
 C:-Both of these
 D:-None of these
 Correct Answer:- Option-C

35. Which of the following is not good for thermoforming?
 A:-PP
 B:-PE
 C:-PF
 D:-PS
 Correct Answer:- Option-C

36. Which of the following is the best for uniform filler dispersion?
 A:-Two roll mill
 B:-Banbury
 C:-Intermix
 D:-Kneader
 Correct Answer:- Option-A

37. Viscosity has the unit
 A:-Pa. S
 B:-N / sq. m
 C:-Mpa
 D:-dN.m.s
 Correct Answer:- Option-A

38. Decrease of viscosity with increasing shear rate is known as
 A:-Newtonian behaviour
 B:-Bingham plastics
 C:-Dilatant behaviour
 D:-Pseudoplastic behaviour
 Correct Answer:- Option-D

39. The unit of shear rate is
 A:-meter per second
 B:-Per second
 C:-meter per second square
 D:-Newton per second
 Correct Answer:- Option-B

40. Yield stress is shown by
 A:-Pseudoplastic materials
 B:-Dilatant materials
 C:-Bingham plastics
 D:-Newtonian liquids
 Correct Answer:- Option-C

41. Thixotropy is associated with reduction in viscosity
 A:-With time at constant shear rate
 B:-With shear rate
 C:-With time and shear rate
 D:-With shear stress
 Correct Answer:- Option-A

42. In rheology relaxation time is defined as
 A:-Viscosity / modulus
 B:-Modulus / yield stress
 C:-Time for 50% reduction in viscosity
 D:-Time for extrudate to recover
 Correct Answer:- Option-A

43. Bagley correction is done to account for
 A:-Exit effect
 B:-Slip at wall
 C:-Stick-slip effect
 D:-Entry effect
 Correct Answer:- Option-D

44. Apparent shear rate for a capillary flow is related to
 A:-Volume flow rate and l/d ratio
 B:-Volume flow rate and capillary diameter
 C:-Shear stress and capillary diameter
 D:-None of these
 Correct Answer:- Option-B

45. In an isometric creep curve
 A:-Stress is plot against strain
 B:-Strain is plotted against time
 C:-Stress is plotted against log time
 D:-Strain is plotted against log time
 Correct Answer:- Option-C

46. Which of the following involves the use of a rotor?
 A:-MDR
 B:-Mooney viscometer
 C:-Rubber process analyzer
 D:-All of these
 Correct Answer:- Option-B

47. The ply angle in radial tyres is close to ________ degrees.
 A:-37
 B:-45
 C:-55
 D:-90
 Correct Answer:- Option-D

48. Which of the following is a slow accelerator?
 A:-DPG
 B:-MBS
 C:-MBTS
 D:-MBT
 Correct Answer:- Option-A

49. Caprolactam disulphide is a
 A:-Activator
 B:-Monomer
 C:-Sulphur donor
 D:-Accelerator
 Correct Answer:- Option-C

50. Chemical mastication is operational after (deg. Centigrade)
 A:-100
 B:-120
 C:-140
 D:-150
 Correct Answer:- Option-B

51. Transmissibility is defined as
 A:-Output amplitude / input amplitude
 B:-Output frequency / input frequency
 C:-Loss modulus / storage modulus
 D:-None of these
 Correct Answer:- Option-A

52. For good vibration isolation
 A:-Transmissibility must be > 1
 B:-Natural frequency must be high
 C:-Natural frequency must be low
 D:-Damping must be high
 Correct Answer:- Option-C

53. DBP number is used to measure
 A:-C black particle size
 B:-C black surface area
 C:-Surface functional group
 D:-C black structure
 Correct Answer:- Option-D

54. BET method uses ________ gas to measure surface area.
 A:-Oxygen
 B:-Helium
 C:-Nitrogen
 D:-Argon
 Correct Answer:- Option-C

55. Si 69 is a
 A:-Coupling agent
 B:-Bonding agent
 C:-Tackifier
 D:-None of these
 Correct Answer:- Option-A

56. Azodicarbonamide is a
 A:-Accelerator
 B:-Blowing agent
 C:-Peptizer
 D:-Activator
 Correct Answer:- Option-B

57. The primary criterion for choosing blend components is
 A:-Tg must be same
 B:-Tg must be close
 C:-Cohesive energy density > 1
 D:-Solubility parameter must be close
 Correct Answer:- Option-D

58. Blend miscibility is studied using a
 A:-DMA
 B:-DSC
 C:-Both of these
 D:-None of these
 Correct Answer:- Option-C

59. Anisotropy is defined as
 A:-Time dependent creep
 B:-Strain dependent stress relaxation
 C:-Temperature dependent modulus
 D:-Direction dependent properties
 Correct Answer:- Option-D

60. In short fiber composite extrusion, fibers are oriented circumferentially in a
 A:-Diverging die
 B:-Converging die
 C:-Capillary die
 D:-Ribbon die
 Correct Answer:- Option-A

61. In blends UCST stands for
 A:-Unit component surface thickness
 B:-Upper critical solution temperature
 C:-Unifiber composite sheet thickness
 D:-None of these
 Correct Answer:- Option-B

62. Spherulites are related to
 A:-Polymer composites
 B:-Polymer blends
 C:-Polymer crystals
 D:-Polymer coatings
 Correct Answer:- Option-C

63. For a 70/30 NR/PE blend which phase morphology is more probable?
 A:-NR is continuous phase
 B:-PE is continuous phase
 C:-They form IPN
 D:-NR & PE form continuous phase
 Correct Answer:- Option-A

64. Which one has molecular level mixing?
 A:-Blend
 B:-Composite
 C:-Alloy
 D:-All of these
 Correct Answer:- Option-C

65. The membrane on rubber particles is
 A:-proteinic
 B:-lipoproteinic
 C:-phospholipoproteinic
 D:-phosphoproteinic
 Correct Answer:- Option-C

66. Which of the following statements is true?
 A:-TSC > DRC
 B:-TSC < DRC
 C:-TSC = DRC
 D:-TSC-DRC < 1
 Correct Answer:- Option-A

67. Mechanical stability test is done on
 A:-Latex
 B:-Unvulcanised rubber
 C:-Vulcanised rubber
 D:-Aged rubber
 Correct Answer:- Option-A

68. The major metal present in sludge removed from latex is
 A:-Fe
 B:-Mg
 C:-Mn
 D:-None of these
 Correct Answer:- Option-B

69. Which of the following is a VFA?
 A:-Stearic acid
 B:-Acetic acid
 C:-Palmitic acid
 D:-Oleic acid
 Correct Answer:- Option-B

70. Which of the following cannot destabilize latex?
 A:-Ammonia
 B:-Acid
 C:-Metal ion
 D:-Positively charged electrode
 Correct Answer:- Option-A

71. Potassium oleate is used in NR foam manufacture as
 A:-Foam stabilizer
 B:-Activator
 C:-Foam promoter
 D:-Antioxidant
 Correct Answer:- Option-C

72. The foaming agent used in NR foam is
 A:-DNPT
 B:-Nitrogen
 C:-Air
 D:-All of these
 Correct Answer:- Option-C

73. For making thick walled dipped products the preferred method is
 A:-Coacervant dipping
 B:-Heat sensitised dipping
 C:-Straight dipping
 D:-Multiple dipping
 Correct Answer:- Option-B

74. In electrodeposition the rubber is deposited on
 A:-Positive electrode
 B:-Semi permeable membrane
 C:-Negative electrode
 D:-All of these
 Correct Answer:- Option-A

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